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Shell Omala Oil 68
Infosafe No.ACH6PVersion No.1.1APPROVED Date2003-05-28Issued ByAPPROVED
1. IDENTIFICATION ON CHEMICAL PRODUCT AND COMPANYA. Product NameShell Omala Oil 68Product Code001A0773
Other NamesNameCodeShell Omala Oil 68140000006363
B. General CharacteristicsBrown. Liquid at ambient temperature. Insoluble in water.C. Hazard ClassificationNot available. D. Usage of ProductGear lubricant. E. Manufacturer InformationShell Oil Products F. Supplier/Distributor InformationHankook ShellAddressSeoul Telephone/Fax NumberTel: 3149-5500 G. Production Department and NameTechnical/Marketing Department Ko Sung-Ho H. First Issue Date18/06/2004I. Revision History and Final Revision DateNot applicable. 2. NAME OF INGREDIENTS AND CONTENTS
IngredientsChemical Name CAS No. Contents Applicable Risk Phrases Highly-refined mineral oils64742-56-9, 64742-65-0, 64742-54-7, 64742-62-7, 64742-56-995-99 %None applicableLubricant additivesSecret0-5 %None applicableTotal 100 %
3. HAZARDS IDENTIFICATIONA. Imminent Hazard and Harmfulness InformationNo specific hazards under normal use conditions. Prolonged or repeated exposure may give rise to dermatitis. Used oil may contain harmful impurities. NFPA Rating: Health = 1, Flammability = 1, Reactivity = 1. B. Effects on EyeExpected to be slightly irritating. C. Effects on SkinExpected to be slightly irritating. D. Effects on InhalingIf mists are inhaled, slight irritation of the respiratory tract may occur. Dizziness and nausea may also occur. E. Effects on IngestionNo data available. F. Symptoms and Signs of Chronic IllnessProlonged and/or repeated contact with products containing mineral oils may result in defatting of the skin, particularly at elevated temperatures. This may lead to irritation and possibly dermatitis, especially under conditions of poor personal hygiene. Skin contact should be minimised. Used oils may contain harmful impurities that have accumulated during use. The concentration of such impurities will depend on use and they may present risks to health and the environment on disposal. ALL used oil should be handled with caution and skin contact avoided as far as possible. 4. FIRST AID MEASURESA. Contact with EyeFlush eye with copious quantities of water. If persistent irritation occurs, obtain medical attention. B. Contact With SkinRemove contaminated clothing and wash affected skin with soap and water. If persistent irritation occurs, obtain medical attention. If high pressure injection injuries occur, obtain medical attention immediately. C. InhalationIn the unlikely event of dizziness or nausea, remove casualty to fresh air. If symptoms persist, obtain medical attention. D. IngestionDo not induce vomiting. Wash out mouth with water and obtain medical attention. E. Advice to DoctorTreat symptomatically. Aspiration into the lungs may result in chemical pneumonitis. Dermatitis may result from prolonged or repeated exposure. 5. FIRE FIGHTING MEASURESA. Flash Point191C (PMCC). B. Auto-Ignition Temperature>320 (typical). C. Flammable LimitsLower Ignition limits1%(V/V) (typical). Upper Ignition limits10%(V/V) (typical). D. Classification under Fire Services Act and the Contents of RegulationsClassified as Class 4, 'Category 3 Tertiary Petroleum' Dangerous Article according to the Fire Services Act. E. Extinguishing MediaFoam and dry chemical powder. Carbon dioxide, sand or earth may be used for small fires only. F. Fire-fighting Method and EquipmentProper protective equipment including breathing apparatus must be worn when approaching a fire in a confined space. G. Harmful Substances Occurring in CombustionCombustion is likely to give rise to a complex mixture of airborne solid and liquid particulates and gases, including carbon monoxide and unidentified organic and inorganic compounds. H. Unsuitable Extinguishing MediaWater in jet. Use of halon extinguishers should be avoided for environmental reasons. 6. ACCIDENTAL RELEASE MEASURESA. Personal PrecautionsAvoid contact with skin and eyes. Wear PVC, Neoprene or nitrile rubber gloves. Wear rubber knee length safety boots and PVC Jacket and Trousers. Wear safety glasses or full face shield if splashes are likely to occur. B. Environmental PrecautionsPrevent from spreading or entering into drains, ditches or rivers by using sand, earth, or other appropriate barriers. Inform local authorities if this cannot be prevented. C. Clean-up MethodsSmall SpillagesAbsorb liquid with sand or earth. Sweep up and remove to a suitable, clearly marked container for disposal in accordance with local regulations. Large SpillagesPrevent from spreading by making a barrier with sand, earth or other containment material. Reclaim liquid directly or in an absorbent. Dispose of as for small spills. 7. HANDLING AND STORAGEA. HandlingUse local exhaust ventilation if there is risk of inhalation of vapours, mists or aerosols. Avoid prolonged or repeated contact with skin. When handling product in drums, safety footwear should be worn and proper handling equipment should be used. Prevent spillages. Cloth, paper and other materials that are used to absorb spills present a fire hazard. Avoid their accumulation by disposing of them safely and immediately. In addition to any specific recommendations given for controls of risks to health, safety and the environment, an assessment of risks must be made to help determine controls appropriate to local circumstances. B. StorageKeep in a cool, dry, well-ventilated place. Use properly labelled and closeable containers. Avoid direct sunlight, heat sources, and strong oxidizing agents. Storage Temperatures0C Minimum. 50C Maximum. Recommended MaterialsFor containers or container linings, use mild steel or high density polyethylene. Unsuitable MaterialsFor containers or container linings, avoid PVC. Other InformationPolyethylene containers should not be exposed to high temperatures because of possible risk of distortion. 8. EXPOSURE CONTROLS, PERSONAL PROTECTIONA. Exposure ControlsUse local exhaust ventilation if there is a risk of inhalation of vapours, mists or aerosols. B. Respiratory ProtectionNot normally required. If oil mist cannot be controlled, a respirator fitted with an organic vapour cartridge combined with a particulate pre-filter should be used. C. Eye ProtectionWear safety glasses or full face shield if splashes are likely to occur. D. Hand ProtectionPVC or nitrile rubber gloves. E. Body ProtectionMinimise all forms of skin contact. Overalls and shoes with oil resistant soles should be worn. Launder overalls and undergarments regularly. F. Hygiene MeasuresNo information. G. Exposure LimitsAll data available on Exposure limits is given below.
Substance Regulations Exposure Duration Exposure Limit Units Notes Oil mist, mineralISHL Article 42; MOL Public Notice No. 1986 - 45 as amended through MOL Public Notice No. 1997-65, Jan. 5, 1998TWA5mg/m3ISHL Article 42; MOL Public Notice No. 1986 - 45 as amended through MOL Public Notice No. 1997-65, Jan. 5, 1998STEL10mg/m3
9. PHYSICAL AND CHEMICAL PROPERTIESA. AppearanceColourBrown. Physical StateLiquid at ambient temperature. B. OdourCharacteristic mineral oil. C. pH ValueData not available. D. Solubility in WaterNegligible. E. Initial Boiling Point>280C. F. Melting PointData not available. G. ExplosivenessData not available. H. OxidationData not available. I. Vapour Pressure6 (typical). L. Vapour Density (Air=1)>1 at 20C. M. Kinematic Viscosity68 mm2/s at 40C. N. Molecular WeightData not available. Other InformationThese characteristics are typical of current product while future production will conform to Shell specification variations may occur. 10. STABILITY AND REACTIVITYA. Chemical StabilityStable. B. Conditions and Substances to be AvoidedMaterials to AvoidStrong oxidizing agents. Conditions to AvoidExtremes of temperature and direct sunlight. C. Hazardous Decomposition ProductsHazardous decomposition products are not expected to form during normal storage. D. Hazardous ReactionNone known. 11. TOXICOLOGICAL INFORMATIONBasis for AssessmentToxicological data have not been determined specifically for this product. Information given is based on a knowledge of the components and the toxicology of similar products. A. Acute Toxicity - OralLD50 expected to be > 2000 mg/kg. B. Acute Toxicity - DermalLD50 expected to be > 2000 mg/kg. C. Acute Toxicity - InhalationNot considered to be an inhalation hazard under normal conditions of use. D. Subacute ToxicityNo data available. E. Chronic ToxicityNo data available. F. MutagenicityNot considered to be a mutagenic hazard. G. Reproductive ToxicityNot considered to be toxic to reproduction. H. CarcinogenicityProduct is based on mineral oils of types shown to be non-carcinogenic in animal skin-painting studies. Other components are not known to be associated with carcinogenic effects. 12. ECOLOGICAL INFORMATIONA. Aquatic and Ecological ToxicityBasis for AssessmentEcotoxicological data have not been determined specifically for this product. Information given is based on a knowledge of the components and the ecotoxicology of similar products. EcotoxicityPoorly soluble mixture. May cause physical fouling of aquatic organisms. Product is expected to be practically non-toxic to aquatic organisms, LL/EL50 >100 mg/l. (LL/EL50 expressed as the nominal amount of product required to prepare aqueous test extract). Mineral oil is not expected to cause any chronic effects to aquatic organisms at concentrations less than 1 mg/l.Other Adverse EffectsNot expected to have ozone depletion potential, photochemical ozone creation potential or global warming potential. Product is a mixture of non-volatile components, which are not expected to be released to air in any significant quantities. B. MobilityLiquid under most environmental conditions. Floats on water. If it enters soil, it will adsorb to soil particles and will not be mobile. C. Residual Property and DecompositionNot expected to be readily biodegradable. Major constituents are expected to be inherently biodegradable, but the product contains components that may persist in the environment. D. Accumulation Possibility on Animal and PlantsContains components with the potential to bioaccumulate. 13. DISPOSAL CONSIDERATIONSA. Status of Regulations under Wastes Control ActFollow the procedure of petroleum product management regulation. This is subject of regulation under the Waste Control Act Article 4, Article 5, Article 25, Article 44 and others. B. How to DisposeDisposition shall be made by entrusting the undertaking to the person who obtained the permission of waste disposal business under the regulation of Clause 3 of Article 26, the person who recycles the waste materials of other persons under the regulation of Clause 2 of Article 44, the person who establishes and manages the waster treatment facility under the regulations of Article 4 or Article 5, or the person who has registered of marine disposition business of the waste materials under the provision of Article 18 of the Prevention of Marine Pollution Act. Prevention of Marine Pollution ActThe pollution to the soil or water quality, because of unauthorized disposition, shall absolutely be prohibited. C. Caution in DisposalRecycle or dispose of in accordance with prevailing regulations, with a recognised collector or contractor. The competence of the contractor to deal satisfactorily with this type of product should be established beforehand. Do not pollute the soil, water or environment with the waste product. 200 litre drums should be emptied and returned to the supplier or sent to a drum reconditioner without removing or defacing markings or labels. Non-reusable small metal and plastic containers should be recycled where possible, or disposed of as domestic refuse. 14. TRANSPORT INFORMATIONA. Classification under Hazardous Substance Vessel Transportation and In-Land Regulation of Safety of Vessels Act and RegulationsThis is not a subject for classification and regulations. B. Caution in TransportationGrounding and impacting shall be avoided. C. Other Classification under the Rules related to Transportation in Other CountriesNot dangerous for transport under UN, IMO, and IATA/ICAO codes. 15. REGULATORY INFORMATIONA. Regulations under Industrial Safety and Health ActArticle 41, Article 69 and Article 72 of industrial Safety and Health Act (Penalty provision when violating) B. Regulations under the Pertinent Laws of Chemical Substance Management of Other MinistriesControl of Harmful Chemical Substances ActUnregulated. Waste Control ActArticles 4,5, 18, 25, 26 and 44 Fire fighting lawNo. 4 type for No. 3 petroleum type. Safety of Vessels ActNot classified. C. Other Regulations under the Laws of Foreign CountriesEC SymbolsNone. EC Risk PhraseNot classified. EC Safety PhraseNot classified. EINECSAll components listed or polymer exempt. TSCA (USA)All components in compliance. Packaging & LabellingSafety data sheet available for professional user on request. 16. OTHER INFORMATIONA. Source of DataBased on an SDS from Shell Lubricants, we, Hankook Shell, translated this MSDS according to a form of Korean Industrial Safety and Health Act 41. B. RestrictionsThis product must not be used in applications other than recommended without first seeking the advice of the SHELL technical department. C. Further InformationThis information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It does not constitute a guarantee for any specific property of the product. End of MSDS
Addendum
Ingredient Name: UOM RiskPhrase
S1 Secret < 5 % Not Classified
S2 Secret < 1 % Not Classified
S3 Secret < 0.1 % Not Classified
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shell omala